PSYCHROMETRIC RELATIONS

  1. Specific (or absolute) humidity, humidity ratio or moisture content, w: It is defined as the ratio of the mass of water vapour to the mass of dry air in a given volume of the mixture.Let pVTm = pressure, volume, absolute temperature and mass respectivelyRMv = gas constant, molecular mass, specific volume, and universal gas constant respectivelySubscripts av = air and vapour respectively.imagesFor air,imagesAnd imagesFor water vapour,imagesSubstituting for mv and ma from these equations in Eq. (20.2), we getimagesNow actual total pressure, pb = pa + pvimagesFor ma = 1 kg, mv = w kg and total mass of moist airimagesFor saturated air, pv = ps and maximum humidity ratioimageswhere ps = partial pressure of air corresponding to saturation temperature i.e. td.
  2. Degree of saturation or percentage humidity, µ: The ratio of actual specific humidity w to the specific humidity ws of saturated air at the same temperature is termed as the degree of saturation. imagesThe degree of saturation is a measure of the capacity of air to absorb moisture.
  3. Relative Humidity (RH or ϕ): It is defined as the ratio of mass of water vapour mv in a certain volume of moist air at a given temperature to the mass of water vapour mvs in the same volume of saturated air at the same temperature. imagesFor a perfect gas pvvv = psvsimages imagesNow imagesimages
  4. Pressure of water vapour:
    1. The partial pressure of water vapour, according to Carrier’s equation, is given by imageswhere pw = saturation pressure corresponding to WBTpb = barometric pressuretd = DBTtw = WBT
    2. Modified Apjohn equation: images
    3. Modified Ferrel equation: images
  5. Vapour density or Absolute humidity:Let pv = density of water vapour corresponding to its partial pressure and DBT, td.pa = density of dry air.Then mv = Vvρv and ma = VaρaimagesSince Va = Vv, therefore,imagesOr ρv = aNow pa Va = maRaTdFor ma = 1 kg, imagesimages images

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